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de Oliveira, Celso R.; Ledvina, Zachary D.; Leonard, Michael D.; Odoh, Samuel O.; Dodson, Craig D.; Jeffrey, Christopher S. (, Frontiers in Natural Products)A novel meroterpenoid cabagranin D was isolated with related neolignans cabagranins A–C from the leaves ofPiper cabagranum(Costa Rica). Cabagranins A–C represent the first examples of 3,3′-neolignans isolated from the plant genusPiper, and the meroterpenoid cabagranin D displays an unprecedented Diels–Alder conjugate of an unsubstituted phenylpropenone and α-phellandrene. Details of the full structural elucidation of these compounds and a discussion of their potential biosynthetic relationships are presented.more » « less
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